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🧪 Chemistry  ·  Solid State  ·  NEET & JEE

In the CsCl structure, the coordination number of each Cs⁺ and each Cl⁻ is:

Answer: 8 and 8.

  • A 4 and 4
  • B 6 and 6
  • C 8 and 8
  • D 4 and 8

Correct answer: C. 8 and 8

Explanation: CsCl has a body-centred cubic arrangement where each Cs⁺ is surrounded by 8 Cl⁻ and vice versa; CN = 8:8.

Cubic Unit Cells: Atom PositionsSimple CubicCN=6, 52.4% packedBody-Centred (BCC)CN=8, 68% packedFace-Centred (FCC)CN=12, 74% packed (densest)Corner atoms (shared by 8 cells) shown lighter; body/face-centre atoms shown solid

The three cubic unit cells: Simple Cubic has atoms only at corners; Body-Centred adds one atom at the centre; Face-Centred adds one atom at the centre of each of the 6 faces, giving the highest packing efficiency.

Concept context

Explore the ordered world of crystalline solids: unit cells, packing, defects, and how structure determines electrical and magnetic properties.

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