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🧪 Chemistry  ·  Solid State  ·  NEET & JEE

In an ionic crystal, if the stoichiometry deviates from the ideal formula (e.g., Fe₀.₉₅O instead of FeO), this is a result of:

Answer: Metal deficiency defect.

  • A Schottky defect
  • B Frenkel defect
  • C Metal deficiency defect
  • D Interstitial defect

Correct answer: C. Metal deficiency defect

Explanation: In FeO, some Fe²⁺ are replaced by Fe³⁺; fewer total iron atoms are needed to balance the oxygen, creating a metal-deficiency (non-stoichiometric) defect.

Cubic Unit Cells: Atom PositionsSimple CubicCN=6, 52.4% packedBody-Centred (BCC)CN=8, 68% packedFace-Centred (FCC)CN=12, 74% packed (densest)Corner atoms (shared by 8 cells) shown lighter; body/face-centre atoms shown solid

The three cubic unit cells: Simple Cubic has atoms only at corners; Body-Centred adds one atom at the centre; Face-Centred adds one atom at the centre of each of the 6 faces, giving the highest packing efficiency.

Concept context

Explore the ordered world of crystalline solids: unit cells, packing, defects, and how structure determines electrical and magnetic properties.

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