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🧪 Chemistry  ·  Solid State  ·  NEET & JEE

In an HCP structure, the coordination number and the fraction of void space are:

Answer: 12 and 26%.

  • A 12 and 26%
  • B 8 and 32%
  • C 6 and 48%
  • D 12 and 36%

Correct answer: A. 12 and 26%

Explanation: HCP has the same coordination number (12) and packing efficiency (74%) as FCC, leaving a void fraction of 1 - 0.74 = 0.26, or 26%.

Cubic Unit Cells: Atom PositionsSimple CubicCN=6, 52.4% packedBody-Centred (BCC)CN=8, 68% packedFace-Centred (FCC)CN=12, 74% packed (densest)Corner atoms (shared by 8 cells) shown lighter; body/face-centre atoms shown solid

The three cubic unit cells: Simple Cubic has atoms only at corners; Body-Centred adds one atom at the centre; Face-Centred adds one atom at the centre of each of the 6 faces, giving the highest packing efficiency.

Concept context

Explore the ordered world of crystalline solids: unit cells, packing, defects, and how structure determines electrical and magnetic properties.

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