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🧪 Chemistry  ·  s-Block Elements  ·  NEET & JEE

Why does LiF have lower solubility in water than LiCl?

Answer: LiF has very high lattice energy; the hydration enthalpy does not overcome it.

  • A LiF has very high lattice energy; the hydration enthalpy does not overcome it
  • B LiF is a mainly covalent compound that resists hydration largely in most textbook accounts
  • C LiCl carries a noticeably higher degree of bond polarity than LiF during normal conditions
  • D LiF exists as a volatile gas under standard room conditions as generally observed

Correct answer: A. LiF has very high lattice energy; the hydration enthalpy does not overcome it

Explanation: LiF: high lattice energy (due to small F-) outweighs hydration energy, so it is sparingly soluble. LiCl has lower lattice energy and dissolves readily.

Flame Test Colours (s-Block Elements)LicrimsonNagolden yellowKlilac/violetCabrick redBaapple green

Each s-block metal ion emits a characteristic flame colour because heating excites electrons to higher energy levels; light is emitted as they fall back, with the colour determined by the specific energy gap.

Concept context

Group 1 (alkali metals) and Group 2 (alkaline earth metals). Learn their reactions with water and air, important compounds like NaOH, Na₂CO₃, and CaCO₃, and anomalous behaviour of lithium and beryllium.

Read the full s-Block Elements notes →