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🧪 Chemistry  ·  s-Block Elements  ·  NEET & JEE

The thermal stability of the carbonates of Group 2 follows the order BeCO<sub>3</sub> < MgCO<sub>3</sub> < CaCO<sub>3</sub> < SrCO<sub>3</sub> < BaCO<sub>3</sub> because, down the group:

Answer: The cation polarises the carbonate ion less, stabilising it.

  • A The cation polarises the carbonate ion less, stabilising it
  • B The cation becomes smaller and far more strongly polarising
  • C Lattice enthalpy increases sharply
  • D The carbonate ion becomes more covalent

Correct answer: A. The cation polarises the carbonate ion less, stabilising it

Explanation: Larger cations down the group have lower polarising power and distort the CO<sub>3</sub><sup>2-</sup> ion less, so the carbonates need higher temperatures to decompose and are thermally more stable.

Flame Test Colours (s-Block Elements)LicrimsonNagolden yellowKlilac/violetCabrick redBaapple green

Each s-block metal ion emits a characteristic flame colour because heating excites electrons to higher energy levels; light is emitted as they fall back, with the colour determined by the specific energy gap.

Concept context

Group 1 (alkali metals) and Group 2 (alkaline earth metals). Learn their reactions with water and air, important compounds like NaOH, Na₂CO₃, and CaCO₃, and anomalous behaviour of lithium and beryllium.

Read the full s-Block Elements notes →