Zaymiey

🧪 Chemistry  ·  s-Block Elements  ·  NEET & JEE

The standard electrode potential E° of Li/Li+ (-3.05 V) is more negative than Na/Na+ (-2.71 V). In terms of reactivity in water, however:

Answer: Na reacts more vigorously with water than Li, despite Li's more negative E°, due to kinetic factors.

  • A Na reacts more vigorously with water than Li, despite Li's more negative E°, due to kinetic factors
  • B Lithium instead reacts noticeably faster with water than sodium does in practice
  • C Both metals react with cold water at an identical and equally vigorous observable rate
  • D The standard electrode potential value alone fully and accurately predicts the reaction rate

Correct answer: A. Na reacts more vigorously with water than Li, despite Li's more negative E°, due to kinetic factors

Explanation: Li's high hydration enthalpy means thermodynamics favours Li strongly, but a thin film of LiOH coats Li and slows the reaction kinetically; Na's film is more reactive/less coherent.

Flame Test Colours (s-Block Elements)LicrimsonNagolden yellowKlilac/violetCabrick redBaapple green

Each s-block metal ion emits a characteristic flame colour because heating excites electrons to higher energy levels; light is emitted as they fall back, with the colour determined by the specific energy gap.

Concept context

Group 1 (alkali metals) and Group 2 (alkaline earth metals). Learn their reactions with water and air, important compounds like NaOH, Na₂CO₃, and CaCO₃, and anomalous behaviour of lithium and beryllium.

Read the full s-Block Elements notes →