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The solubility of alkaline earth metal hydroxides increases down the group (Be(OH)<sub>2</sub> < Mg(OH)<sub>2</sub> < ... < Ba(OH)<sub>2</sub>) mainly because:

Answer: Lattice enthalpy decreases faster than hydration enthalpy down the group.

  • A Hydration enthalpy increases down the group
  • B Lattice enthalpy decreases faster than hydration enthalpy down the group
  • C The hydroxides become increasingly covalent and less ionic down the group
  • D Lattice enthalpy increases down the group

Correct answer: B. Lattice enthalpy decreases faster than hydration enthalpy down the group

Explanation: Down the group the decrease in lattice enthalpy outweighs the decrease in hydration enthalpy, so the net energetics favour greater solubility of the heavier hydroxides.

Flame Test Colours (s-Block Elements)LicrimsonNagolden yellowKlilac/violetCabrick redBaapple green

Each s-block metal ion emits a characteristic flame colour because heating excites electrons to higher energy levels; light is emitted as they fall back, with the colour determined by the specific energy gap.

Concept context

Group 1 (alkali metals) and Group 2 (alkaline earth metals). Learn their reactions with water and air, important compounds like NaOH, Na₂CO₃, and CaCO₃, and anomalous behaviour of lithium and beryllium.

Read the full s-Block Elements notes →