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🧪 Chemistry  ·  s-Block Elements  ·  NEET & JEE

A blue solution of sodium in liquid ammonia conducts electricity and is strongly reducing. On standing, the blue colour fades and the conductivity changes because:

Answer: Ammoniated electrons slowly convert to sodium amide with evolution of dihydrogen.

  • A Sodium metal precipitates out unchanged
  • B Ammoniated electrons slowly convert to sodium amide with evolution of dihydrogen
  • C The dissolved sodium is slowly oxidised to sodium hydroxide and nitrogen gas
  • D Ammonia is oxidised to nitrogen gas

Correct answer: B. Ammoniated electrons slowly convert to sodium amide with evolution of dihydrogen

Explanation: The blue colour and conductivity arise from ammoniated electrons. On standing these react: Na + NH<sub>3</sub> → NaNH<sub>2</sub> + ½H<sub>2</sub>, so the colour fades as amide forms and H<sub>2</sub> is released.

Flame Test Colours (s-Block Elements)LicrimsonNagolden yellowKlilac/violetCabrick redBaapple green

Each s-block metal ion emits a characteristic flame colour because heating excites electrons to higher energy levels; light is emitted as they fall back, with the colour determined by the specific energy gap.

Concept context

Group 1 (alkali metals) and Group 2 (alkaline earth metals). Learn their reactions with water and air, important compounds like NaOH, Na₂CO₃, and CaCO₃, and anomalous behaviour of lithium and beryllium.

Read the full s-Block Elements notes →