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🧪 Chemistry  ·  Polymers  ·  NEET & JEE

In the Ziegler-Natta catalyst system, which two components are essential?

Answer: TiCl 4 and Al(C 2 H 5 ) 3.

  • A TiCl<sub>4</sub> and Al(C<sub>2</sub>H<sub>5</sub>)<sub>3</sub>
  • B FeCl<sub>3</sub> and BF<sub>3</sub>
  • C BF<sub>3</sub> and H<sub>2</sub>SO<sub>4</sub>
  • D TiCl<sub>4</sub> and H<sub>2</sub>O

Correct answer: A. TiCl<sub>4</sub> and Al(C<sub>2</sub>H<sub>5</sub>)<sub>3</sub>

Explanation: Ziegler-Natta catalyst consists of a transition metal halide (TiCl<sub>4</sub>) and an organoaluminium compound (triethylaluminium).

Addition vs Condensation PolymerisationAddition (e.g. polythene)n (CH₂=CH₂)-[-CH₂-CH₂-]ₙ-No atoms lost - monomers just join at the double bondCondensation (e.g. Nylon-6,6)HOOC-R-COOH + H₂N-R'-NH₂-[-CO-R-CO-NH-R'-NH-]ₙ-+ n H₂OA small molecule (water here) is eliminated at EVERY linking step

Addition polymerisation simply links monomers containing a double bond with nothing left over, while condensation polymerisation joins two different monomers through a reaction (often forming an ester or amide bond) that releases a small molecule like water at each step.

Concept context

Large molecules made of repeating monomer units. Covers addition and condensation polymerisation, natural and synthetic polymers (nylon, PVC, Bakelite, natural rubber), and their real-world industrial applications.

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