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🧪 Chemistry  ·  Polymers  ·  NEET & JEE

Cross-linking in a polymer:

Answer: Increases rigidity and reduces solubility.

  • A Increases rigidity and reduces solubility
  • B Decreases the melting point by disrupting chain packing
  • C Increases flexibility by allowing chains to slide past each other
  • D Increases solubility by exposing more polar groups to solvent

Correct answer: A. Increases rigidity and reduces solubility

Explanation: Cross-links (covalent bonds between chains) prevent chain movement, increasing hardness, rigidity, and reducing solubility.

Addition vs Condensation PolymerisationAddition (e.g. polythene)n (CH₂=CH₂)-[-CH₂-CH₂-]ₙ-No atoms lost - monomers just join at the double bondCondensation (e.g. Nylon-6,6)HOOC-R-COOH + H₂N-R'-NH₂-[-CO-R-CO-NH-R'-NH-]ₙ-+ n H₂OA small molecule (water here) is eliminated at EVERY linking step

Addition polymerisation simply links monomers containing a double bond with nothing left over, while condensation polymerisation joins two different monomers through a reaction (often forming an ester or amide bond) that releases a small molecule like water at each step.

Concept context

Large molecules made of repeating monomer units. Covers addition and condensation polymerisation, natural and synthetic polymers (nylon, PVC, Bakelite, natural rubber), and their real-world industrial applications.

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