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🧪 Chemistry  ·  p-Block Elements (Groups 15 to 18)  ·  NEET & JEE

Which reaction produces chlorine gas industrially (electrolytic process)?

Answer: Electrolysis of brine (NaCl solution) at the anode: 2Cl- → Cl 2 + 2e-.

  • A Electrolysis of brine (NaCl solution) at the anode: 2Cl- → Cl<sub>2</sub> + 2e-
  • B The thermal decomposition of solid sodium chloride at high temperature
  • C The laboratory reaction of concentrated HCl with solid MnO<sub>2</sub>
  • D The direct combustion of sodium metal in chlorine gas

Correct answer: A. Electrolysis of brine (NaCl solution) at the anode: 2Cl- → Cl<sub>2</sub> + 2e-

Explanation: The chlor-alkali process electrolyses concentrated NaCl solution; Cl<sub>2</sub> is liberated at the anode, NaOH at the cathode.

Xenon tetrafluoride XeF4: a central xenon bonded to four fluorine atoms in a square-planar arrangement with two lone pairs above and below, Xe-F bond length 194 pm.

Xenon tetrafluoride (XeF4) has six electron domains around xenon — four Xe–F bonds plus two lone pairs. The lone pairs occupy opposite axial positions, leaving the four fluorine atoms in a square-planar shape (Xe–F ≈ 194 pm). Image: ChemSim, Public Domain, via Wikimedia Commons.

Concept context

Covers the nitrogen family (Group 15), oxygen family (Group 16), halogens (Group 17), and noble gases (Group 18). One of the highest-weightage inorganic chapters in NEET and JEE - includes preparation and properties of HNO₃, H₂SO₄, interhalogens, and xenon compounds.

Read the full p-Block Elements (Groups 15 to 18) notes →