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🧪 Chemistry  ·  p-Block Elements (Groups 15 to 18)  ·  NEET & JEE

The reaction 2SO<sub>2</sub> + O<sub>2</sub> ⇌ 2SO<sub>3</sub> in the Contact process is exothermic. To maximise yield:

Answer: Low temperature and high pressure (Le Chatelier), but kinetics require compromise at ~450°C and ~1-2 atm.

  • A Low temperature and high pressure (Le Chatelier), but kinetics require compromise at ~450°C and ~1-2 atm
  • B Operating at the highest practical reactor temperature regardless of the resulting yield as frequently described
  • C Maintaining a very low pressure throughout the entire reactor vessel times in most textbook accounts
  • D Combining a high reactor temperature with a low operating pressure to maximise yield during normal conditions

Correct answer: A. Low temperature and high pressure (Le Chatelier), but kinetics require compromise at ~450°C and ~1-2 atm

Explanation: Higher yield thermodynamically at lower T (exothermic), but too low T makes reaction too slow. ~450°C is the kinetic/thermodynamic compromise.

Xenon tetrafluoride XeF4: a central xenon bonded to four fluorine atoms in a square-planar arrangement with two lone pairs above and below, Xe-F bond length 194 pm.

Xenon tetrafluoride (XeF4) has six electron domains around xenon — four Xe–F bonds plus two lone pairs. The lone pairs occupy opposite axial positions, leaving the four fluorine atoms in a square-planar shape (Xe–F ≈ 194 pm). Image: ChemSim, Public Domain, via Wikimedia Commons.

Concept context

Covers the nitrogen family (Group 15), oxygen family (Group 16), halogens (Group 17), and noble gases (Group 18). One of the highest-weightage inorganic chapters in NEET and JEE - includes preparation and properties of HNO₃, H₂SO₄, interhalogens, and xenon compounds.

Read the full p-Block Elements (Groups 15 to 18) notes →