Zaymiey

🧪 Chemistry  ·  Isolation of Elements  ·  NEET & JEE

In the hottest lower zone of the blast furnace, iron oxide is reduced chiefly by:

Answer: coke (carbon).

  • A carbon monoxide (CO)
  • B coke (carbon)
  • C limestone
  • D hydrogen gas

Correct answer: B. coke (carbon)

Explanation: In the very hot lower region (about 1123-1873 K) the FeO is reduced directly by coke (carbon): FeO + C gives Fe + CO; in cooler upper zones CO is the main reductant.

Ellingham Diagram (simplified)T (°C)ΔG° (more negative ↑)CO + ½O₂ → CO₂ (carbon line)2Al + 1.5O₂ → Al₂O₃2Mg + O₂ → 2MgOcrossover: above this T, carbon reduces Al₂O₃

An Ellingham diagram plots ΔG° of oxide formation against temperature for different metals; whichever line is LOWER (more negative ΔG°) at a given temperature reduces the oxide of any metal whose line sits above it - the basis of carbon reduction (Fe, Zn) vs electrolytic reduction (Al, Mg, Na) decisions.

Concept context

The science of extracting metals from ores and refining them for use. Covers concentration methods, reduction techniques, refining processes, and the thermodynamic principles that govern metal extraction.

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