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🧪 Chemistry  ·  Hydrocarbons  ·  NEET & JEE

Which rule predicts the major product during addition of HX to an unsymmetrical alkene?

Answer: Markovnikov rule.

  • A Huckel rule
  • B Markovnikov rule
  • C Baeyer rule
  • D Saytzeff rule

Correct answer: B. Markovnikov rule

Explanation: Markovnikov rule states that hydrogen attaches to the carbon already having more hydrogen atoms.

Hybridisation and Bonding in HydrocarbonsCCEthane: sp³, single bond109.5°, free rotationCCEthene: sp², double bond120°, planar, NO rotationCCEthyne: sp, triple bond180°, linearMore bonds between the same 2 carbons = shorter, stronger, but more reactive bond

Going from a single to a triple bond between carbons increases the s-character of hybridisation (sp³→sp²→sp), shortening the bond and locking the geometry, while increasing π-bond reactivity (alkenes and alkynes readily undergo addition reactions that alkanes don't).

Concept context

The simplest organic compounds made only of carbon and hydrogen. Covers alkanes, alkenes, alkynes, and aromatic compounds like benzene. Learn preparation methods, key reactions, and physical properties.

Read the full Hydrocarbons notes →