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🧪 Chemistry  ·  Hydrocarbons  ·  NEET & JEE

Which carbocation is formed during Markovnikov addition of HBr to propene?

Answer: Secondary carbocation.

  • A Methyl carbocation
  • B Primary carbocation
  • C Secondary carbocation
  • D Tertiary carbocation

Correct answer: C. Secondary carbocation

Explanation: The more stable secondary carbocation forms during Markovnikov addition to propene.

Hybridisation and Bonding in HydrocarbonsCCEthane: sp³, single bond109.5°, free rotationCCEthene: sp², double bond120°, planar, NO rotationCCEthyne: sp, triple bond180°, linearMore bonds between the same 2 carbons = shorter, stronger, but more reactive bond

Going from a single to a triple bond between carbons increases the s-character of hybridisation (sp³→sp²→sp), shortening the bond and locking the geometry, while increasing π-bond reactivity (alkenes and alkynes readily undergo addition reactions that alkanes don't).

Concept context

The simplest organic compounds made only of carbon and hydrogen. Covers alkanes, alkenes, alkynes, and aromatic compounds like benzene. Learn preparation methods, key reactions, and physical properties.

Read the full Hydrocarbons notes →