Answer: 2-bromobutane.
- A 1-bromobutane
- B 2-bromobutane
- C 1-bromo-2-methylpropane
- D 2-bromo-2-methylpropane
Correct answer: B. 2-bromobutane
Explanation: Protonation gives the more stable secondary carbocation at C-2, so Br adds there to give 2-bromobutane as the major product.
Going from a single to a triple bond between carbons increases the s-character of hybridisation (sp³→sp²→sp), shortening the bond and locking the geometry, while increasing π-bond reactivity (alkenes and alkynes readily undergo addition reactions that alkanes don't).
Concept context
The simplest organic compounds made only of carbon and hydrogen. Covers alkanes, alkenes, alkynes, and aromatic compounds like benzene. Learn preparation methods, key reactions, and physical properties.