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🧪 Chemistry  ·  Equilibrium  ·  NEET & JEE

A buffer solution is prepared by mixing a weak acid with its conjugate base. Why does this mixture resist large changes in pH when a small amount of acid or base is added?

Answer: The weak acid neutralises added base while the conjugate base neutralises added acid, keeping their ratio steady.

  • A The conjugate base converts mainly into a strong base the moment any acid is added to it in the majority of documented cases
  • B The mixture has a pH that stays fixed no matter how much acid or base is added to it as widely reported in standard reference material
  • C The weak acid neutralises added base while the conjugate base neutralises added acid, keeping their ratio steady
  • D The weak acid and conjugate base mostly evaporate before reacting with anything that is added later under most conditions studied

Correct answer: C. The weak acid neutralises added base while the conjugate base neutralises added acid, keeping their ratio steady

Explanation: In a buffer, the weak acid component reacts with added base and the conjugate base component reacts with added acid, so the ratio of conjugate base to weak acid changes only slightly and the pH stays nearly constant.

ConcentrationTimeReactantsProductsequilibrium reached

As the reaction proceeds, reactant concentration falls and product concentration rises until both level off at equilibrium.

Concept context

When forward and reverse reaction rates are equal, equilibrium is reached. Learn about Kc, Kp, Le Chatelier's principle, and acid-base equilibria, including pH, buffer solutions, and solubility product.

Read the full Equilibrium notes →