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🧪 Chemistry  ·  Environmental Chemistry  ·  NEET & JEE

Why can a single CFC-derived Cl radical destroy approximately 10<sup>5</sup> ozone molecules?

Answer: Cl is regenerated unchanged at the end of each catalytic cycle, repeating the process thousands of times.

  • A Each CFC molecule releases 10<sup>5</sup> Cl radicals when it absorbs UV
  • B Cl reacts with multiple O<sub>3</sub> molecules simultaneously in a single collision
  • C Cl is regenerated unchanged at the end of each catalytic cycle, repeating the process thousands of times
  • D The reaction requires only visible light and produces Cl<sub>2</sub>, which attacks further O<sub>3</sub> more efficiently

Correct answer: C. Cl is regenerated unchanged at the end of each catalytic cycle, repeating the process thousands of times

Explanation: The cycle is: Cl + O<sub>3</sub> → ClO + O<sub>2</sub> (step 1); ClO + O → Cl + O<sub>2</sub> (step 2). Cl is consumed in step 1 but regenerated in step 2 - it acts as a catalyst. A single Cl atom repeats this cycle approximately 10<sup>5</sup> times before being removed by other atmospheric reactions, making the damage enormous.

Classical (London) SmogSources: coal burningSO₂ + particulates + fogReducing typeConditions: cold, humid,early morning, winterVisibility: very low (fog)London, 1952 - ~4000 deathsHarms: eyes, lungs, bronchitisPhotochemical (LA) SmogSources: vehicles, industriesNOx + hydrocarbons + UVOxidising typeConditions: warm, sunny,afternoon, summerProducts: O₃, PAN, acroleinLos Angeles (common in cities)Harms: eyes, rubber cracking

Classical smog is a reducing mixture of SO₂ and fog, while photochemical smog is an oxidising mixture generated by UV-driven reactions of NOx and hydrocarbons.

Concept context

Understand how human activities alter the atmosphere, water, and soil. Covers air pollutants, smog types, ozone depletion, acid rain, greenhouse effect, water and soil pollution, and the principles of green chemistry.

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