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🧪 Chemistry  ·  Environmental Chemistry  ·  NEET & JEE

Which class of compounds is primarily responsible for catalytic depletion of the stratospheric ozone layer?

Answer: Chlorofluorocarbons (CFCs).

  • A Chlorofluorocarbons (CFCs)
  • B Carbon dioxide according to standard textbooks
  • C Methane in general practice
  • D Water vapour as frequently described

Correct answer: A. Chlorofluorocarbons (CFCs)

Explanation: CFCs (chlorofluorocarbons, also called Freons) migrate to the stratosphere where short-wavelength UV breaks the C-Cl bond, releasing Cl radicals. Each Cl radical destroys approximately 10<sup>5</sup> ozone molecules in a catalytic cycle before being removed. CO<sub>2</sub> and CH<sub>4</sub> are greenhouse gases but do not deplete ozone.

Classical (London) SmogSources: coal burningSO₂ + particulates + fogReducing typeConditions: cold, humid,early morning, winterVisibility: very low (fog)London, 1952 - ~4000 deathsHarms: eyes, lungs, bronchitisPhotochemical (LA) SmogSources: vehicles, industriesNOx + hydrocarbons + UVOxidising typeConditions: warm, sunny,afternoon, summerProducts: O₃, PAN, acroleinLos Angeles (common in cities)Harms: eyes, rubber cracking

Classical smog is a reducing mixture of SO₂ and fog, while photochemical smog is an oxidising mixture generated by UV-driven reactions of NOx and hydrocarbons.

Concept context

Understand how human activities alter the atmosphere, water, and soil. Covers air pollutants, smog types, ozone depletion, acid rain, greenhouse effect, water and soil pollution, and the principles of green chemistry.

Read the full Environmental Chemistry notes →