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Why does the conductivity of a strong electrolyte solution decrease as its concentration increases, even though molar conductivity is being measured?

Answer: Increased ionic interactions at higher concentration reduce the ease with which ions move and carry charge per mole.

  • A Increased ionic interactions at higher concentration reduce the ease with which ions move and carry charge per mole
  • B Water molecules dissociate the electrolyte less readily once concentration rises beyond a certain point in most observed cases
  • C Higher concentration generally turns a strong electrolyte into something closer to a weak electrolyte under typical physiological conditions
  • D Strong electrolytes break down into neutral molecules at higher concentration, reducing the number of ions according to standard texts

Correct answer: A. Increased ionic interactions at higher concentration reduce the ease with which ions move and carry charge per mole

Explanation: As concentration increases, inter-ionic attractions become more significant, which reduces ionic mobility and lowers the molar conductivity, even though total conductivity may rise due to more ions being present.

ZnSO4 solutionCuSO4 solutionZnCuAnode (-)Cathode (+)oxidationreductionVSalt bridgee- flow

In a Daniell cell, electrons flow externally from the zinc anode (oxidation) through the voltmeter to the copper cathode (reduction), while the salt bridge completes the circuit.

Concept context

Explore the link between chemical reactions and electricity. Covers galvanic cells, electrolysis, standard electrode potentials, the Nernst equation, and real-world applications like batteries and corrosion.

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