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🧪 Chemistry  ·  d- and f-Block Elements  ·  NEET & JEE

The 18-electron rule in organometallics states that:

Answer: Stable transition metal complexes have 18 electrons in the valence shell (sum of metal d electrons + ligand electrons).

  • A Stable transition metal complexes have 18 electrons in the valence shell (sum of metal d electrons + ligand electrons)
  • B Every transition metal atom is said to contain exactly 18 neutrons within its nucleus as frequently described in most textbook accounts
  • C A maximum of 18 separate individual ligands can ever coordinate to one single metal centre during normal conditions
  • D Transition metals are said to be capable of exhibiting up to 18 distinct oxidation states as generally observed in typical laboratory settings

Correct answer: A. Stable transition metal complexes have 18 electrons in the valence shell (sum of metal d electrons + ligand electrons)

Explanation: The 18-electron rule (EAN rule): stable organometallic complexes have 18 electrons in the metal valence shell (like a noble gas configuration for the metal).

Colours of Common Transition Metal Ions (Aqueous)Cu²⁺ blueFe²⁺ pale greenFe³⁺ brown-yellowMn²⁺ pale pinkNi²⁺/Cr³⁺ greenColour arises from d-d electron transitions - d⁰ ions like Sc³⁺, Ti⁴⁺ are colourless

Aqueous solutions of transition metal ions show characteristic colours caused by electrons absorbing visible light to jump between split d-orbitals; the exact colour depends on the metal, its oxidation state, and surrounding ligands.

Concept context

Transition metals (d-block) and lanthanides/actinides (f-block). Known for coloured compounds, variable oxidation states, complex formation, and catalytic properties. Frequently tested in JEE and NEET.

Read the full d- and f-Block Elements notes →