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🧪 Chemistry  ·  d- and f-Block Elements  ·  NEET & JEE

Lanthanide contraction refers to:

Answer: Progressive decrease in atomic/ionic radii from La to Lu due to poor shielding by 4f electrons.

  • A Progressive decrease in atomic/ionic radii from La to Lu due to poor shielding by 4f electrons
  • B A steady increase in both atomic and ionic radii moving from La all the way to Lu
  • C The spontaneous radioactive decay process observed uniformly across the whole lanthanide series
  • D The gradual stepwise loss of all fourteen 4f electrons moving from La through to Lu

Correct answer: A. Progressive decrease in atomic/ionic radii from La to Lu due to poor shielding by 4f electrons

Explanation: As 4f electrons are added across the lanthanide series, poor shielding by 4f orbitals allows increasing nuclear charge to contract the atom/ion progressively.

Colours of Common Transition Metal Ions (Aqueous)Cu²⁺ blueFe²⁺ pale greenFe³⁺ brown-yellowMn²⁺ pale pinkNi²⁺/Cr³⁺ greenColour arises from d-d electron transitions - d⁰ ions like Sc³⁺, Ti⁴⁺ are colourless

Aqueous solutions of transition metal ions show characteristic colours caused by electrons absorbing visible light to jump between split d-orbitals; the exact colour depends on the metal, its oxidation state, and surrounding ligands.

Concept context

Transition metals (d-block) and lanthanides/actinides (f-block). Known for coloured compounds, variable oxidation states, complex formation, and catalytic properties. Frequently tested in JEE and NEET.

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