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🧪 Chemistry  ·  d- and f-Block Elements  ·  NEET & JEE

In the disproportionation of MnO42- in acidic solution:

Answer: 3MnO42- + 4H+ → 2MnO4- + MnO2 + 2H2O (Mn goes from +6 to +7 and +4).

  • A 3MnO42- + 4H+ → 2MnO4- + MnO2 + 2H2O (Mn goes from +6 to +7 and +4)
  • B Manganese remains largely in the +6 oxidation state throughout
  • C Manganese is largely reduced down to the +2 oxidation state during normal conditions
  • D No reaction occurs when MnO42- is acidified as generally observed

Correct answer: A. 3MnO42- + 4H+ → 2MnO4- + MnO2 + 2H2O (Mn goes from +6 to +7 and +4)

Explanation: Manganate (Mn +6) is unstable in acid and disproportionates to permanganate (Mn +7) and MnO2 (Mn +4).

Colours of Common Transition Metal Ions (Aqueous)Cu²⁺ blueFe²⁺ pale greenFe³⁺ brown-yellowMn²⁺ pale pinkNi²⁺/Cr³⁺ greenColour arises from d-d electron transitions - d⁰ ions like Sc³⁺, Ti⁴⁺ are colourless

Aqueous solutions of transition metal ions show characteristic colours caused by electrons absorbing visible light to jump between split d-orbitals; the exact colour depends on the metal, its oxidation state, and surrounding ligands.

Concept context

Transition metals (d-block) and lanthanides/actinides (f-block). Known for coloured compounds, variable oxidation states, complex formation, and catalytic properties. Frequently tested in JEE and NEET.

Read the full d- and f-Block Elements notes →