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🧪 Chemistry  ·  d- and f-Block Elements  ·  NEET & JEE

Copper is the only 3d metal that does not liberate hydrogen from dilute acids mainly because it has:

Answer: a positive standard reduction potential (E° of Cu 2+ /Cu).

  • A a very high hydration enthalpy and atomisation energy
  • B a positive standard reduction potential (E° of Cu<sup>2+</sup>/Cu)
  • C a completely filled 4s orbital
  • D no unpaired electrons

Correct answer: B. a positive standard reduction potential (E° of Cu<sup>2+</sup>/Cu)

Explanation: The high sum of its enthalpies of atomisation and ionisation is not balanced by hydration, giving Cu a positive E°(Cu<sup>2+</sup>/Cu). So it is not oxidised by H<sup>+</sup> of dilute acids.

Colours of Common Transition Metal Ions (Aqueous)Cu²⁺ blueFe²⁺ pale greenFe³⁺ brown-yellowMn²⁺ pale pinkNi²⁺/Cr³⁺ greenColour arises from d-d electron transitions - d⁰ ions like Sc³⁺, Ti⁴⁺ are colourless

Aqueous solutions of transition metal ions show characteristic colours caused by electrons absorbing visible light to jump between split d-orbitals; the exact colour depends on the metal, its oxidation state, and surrounding ligands.

Concept context

Transition metals (d-block) and lanthanides/actinides (f-block). Known for coloured compounds, variable oxidation states, complex formation, and catalytic properties. Frequently tested in JEE and NEET.

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