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🧪 Chemistry  ·  d- and f-Block Elements  ·  NEET & JEE

Among Ti<sup>3+</sup>, V<sup>3+</sup>, Cr<sup>3+</sup> and Mn<sup>2+</sup>, the ion with the highest spin-only magnetic moment is:

Answer: Mn 2+.

  • A Ti<sup>3+</sup>
  • B Mn<sup>2+</sup>
  • C Cr<sup>3+</sup>
  • D V<sup>3+</sup>

Correct answer: B. Mn<sup>2+</sup>

Explanation: Mn<sup>2+</sup> is d<sup>5</sup> with 5 unpaired electrons (5.92 BM), more than Ti<sup>3+</sup> (d<sup>1</sup>), V<sup>3+</sup> (d<sup>2</sup>) or Cr<sup>3+</sup> (d<sup>3</sup>).

Colours of Common Transition Metal Ions (Aqueous)Cu²⁺ blueFe²⁺ pale greenFe³⁺ brown-yellowMn²⁺ pale pinkNi²⁺/Cr³⁺ greenColour arises from d-d electron transitions - d⁰ ions like Sc³⁺, Ti⁴⁺ are colourless

Aqueous solutions of transition metal ions show characteristic colours caused by electrons absorbing visible light to jump between split d-orbitals; the exact colour depends on the metal, its oxidation state, and surrounding ligands.

Concept context

Transition metals (d-block) and lanthanides/actinides (f-block). Known for coloured compounds, variable oxidation states, complex formation, and catalytic properties. Frequently tested in JEE and NEET.

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