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🧪 Chemistry  ·  Chemistry in Everyday Life  ·  NEET & JEE

Polymers used to make biodegradable sutures, such as poly(beta-hydroxybutyrate-co-beta-hydroxyvalerate) (PHBV), break down inside the body over time. What structural feature of such polymers makes them susceptible to this breakdown, unlike polyethylene?

Answer: They contain ester linkages in the backbone that can be hydrolysed by water and enzymes present in body tissue.

  • A They are built from monomers with much higher molecular mass than polyethylene, which slows their breakdown instead
  • B They are cross-linked thermosetting polymers, a structural feature that usually resists chemical breakdown
  • C They contain mainly carbon-carbon single bonds, similar to the bonds found throughout polyethylene chains
  • D They contain ester linkages in the backbone that can be hydrolysed by water and enzymes present in body tissue

Correct answer: D. They contain ester linkages in the backbone that can be hydrolysed by water and enzymes present in body tissue

Explanation: Biodegradable polymers like PHBV have hydrolysable ester bonds in the main chain, so water and tissue enzymes can cleave them over time; polyethylene's all-carbon backbone resists such hydrolysis.

Micelle Formation: How Soap Removes Greasegrease / oilhydrophobic tail (in oil) - hydrophilic head (in water, blue circles)

The hydrophobic hydrocarbon tail of each soap/detergent molecule dissolves into an oily dirt droplet, while the hydrophilic (ionic) head stays in the surrounding water - trapping the grease inside a micelle that rinses away with water.

Concept context

Drugs and how they interact with biological targets, chemicals in food, and cleansing agents (soaps and detergents) - chemistry applied directly to daily life and healthcare.

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