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🧪 Chemistry  ·  Chemistry in Everyday Life  ·  NEET & JEE

Cationic detergents, used mainly in hair conditioners and as germicides, differ from anionic detergents in which structural feature?

Answer: Their hydrophilic part carries a positively charged nitrogen atom instead of a negative sulphonate group.

  • A They have a noticeably shorter hydrophobic hydrocarbon chain attached to their polar head group under usual circumstances
  • B Their hydrophilic part carries a positively charged nitrogen atom instead of a negative sulphonate group
  • C They are built mainly from sugar-based carbohydrate units rather than long hydrocarbon chains according to most studies
  • D They mix poorly with water and instead form micelles mainly within non-polar oils in the majority of documented cases

Correct answer: B. Their hydrophilic part carries a positively charged nitrogen atom instead of a negative sulphonate group

Explanation: Cationic detergents have a quaternary ammonium group with a positive charge as the hydrophilic part, unlike anionic detergents whose hydrophilic head carries a negative charge.

Micelle Formation: How Soap Removes Greasegrease / oilhydrophobic tail (in oil) - hydrophilic head (in water, blue circles)

The hydrophobic hydrocarbon tail of each soap/detergent molecule dissolves into an oily dirt droplet, while the hydrophilic (ionic) head stays in the surrounding water - trapping the grease inside a micelle that rinses away with water.

Concept context

Drugs and how they interact with biological targets, chemicals in food, and cleansing agents (soaps and detergents) - chemistry applied directly to daily life and healthcare.

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