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🧪 Chemistry  ·  Chemistry in Everyday Life  ·  NEET & JEE

Branched-chain alkylbenzene sulphonate detergents are considered more environmentally problematic than their straight-chain counterparts because they are:

Answer: Non-biodegradable, since bacterial enzymes cannot break down the branched chain efficiently.

  • A Generally more expensive to manufacture on an industrial scale according to conventional understanding
  • B Non-biodegradable, since bacterial enzymes cannot break down the branched chain efficiently
  • C More acutely toxic to aquatic organisms on direct contact with the water in routine practice
  • D Less effective overall at removing grease and oily soils from fabric overall in most cases

Correct answer: B. Non-biodegradable, since bacterial enzymes cannot break down the branched chain efficiently

Explanation: Bacterial degradation works efficiently on unbranched hydrocarbon chains. Branching disrupts this enzymatic breakdown, so branched detergents persist in water bodies as pollutants, unlike straight-chain (linear) detergents.

Micelle Formation: How Soap Removes Greasegrease / oilhydrophobic tail (in oil) - hydrophilic head (in water, blue circles)

The hydrophobic hydrocarbon tail of each soap/detergent molecule dissolves into an oily dirt droplet, while the hydrophilic (ionic) head stays in the surrounding water - trapping the grease inside a micelle that rinses away with water.

Concept context

Drugs and how they interact with biological targets, chemicals in food, and cleansing agents (soaps and detergents) - chemistry applied directly to daily life and healthcare.

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