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🧪 Chemistry  ·  Aldehydes, Ketones and Carboxylic Acids  ·  NEET & JEE

Which product is formed in the Perkin reaction of benzaldehyde with acetic anhydride?

Answer: Cinnamic acid.

  • A Cinnamic acid
  • B Salicylic acid
  • C Benzoic acid
  • D Benzyl alcohol

Correct answer: A. Cinnamic acid

Explanation: Perkin reaction between benzaldehyde and acetic anhydride gives cinnamic acid.

Nucleophilic Addition to C=ONu:-CORR'CO-RR'Nu

Curved arrows show the nucleophile attacking the carbonyl carbon while the C=O pi electrons move onto oxygen, giving a tetrahedral alkoxide intermediate.

Concept context

Aldehydes, ketones, carboxylic acids, and their derivatives (esters, amides, acid chlorides). Key reactions include nucleophilic addition, Aldol condensation, Cannizzaro, and Claisen. Very heavily tested in JEE and NEET.

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