Answer: CCl 3 COOH.
- A CH<sub>3</sub>COOH
- B CCl<sub>3</sub>COOH
- C CH<sub>3</sub>CH<sub>2</sub>COOH
- D HCOOH
Correct answer: B. CCl<sub>3</sub>COOH
Explanation: Three electron-withdrawing chlorines strongly stabilise the carboxylate, making trichloroacetic acid by far the strongest here.
Curved arrows show the nucleophile attacking the carbonyl carbon while the C=O pi electrons move onto oxygen, giving a tetrahedral alkoxide intermediate.
Concept context
Aldehydes, ketones, carboxylic acids, and their derivatives (esters, amides, acid chlorides). Key reactions include nucleophilic addition, Aldol condensation, Cannizzaro, and Claisen. Very heavily tested in JEE and NEET.
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