Zaymiey

🧪 Chemistry  ·  Aldehydes, Ketones and Carboxylic Acids  ·  NEET & JEE

Which compound gives a positive iodoform test?

Answer: Propan-2-ol.

  • A Propan-2-ol
  • B Propan-1-ol
  • C Dimethyl ether
  • D Benzaldehyde

Correct answer: A. Propan-2-ol

Explanation: Propan-2-ol is oxidised to acetone (CH<sub>3</sub>COCH<sub>3</sub>) under the iodoform conditions, giving a positive test.

Nucleophilic Addition to C=ONu:-CORR'CO-RR'Nu

Curved arrows show the nucleophile attacking the carbonyl carbon while the C=O pi electrons move onto oxygen, giving a tetrahedral alkoxide intermediate.

Concept context

Aldehydes, ketones, carboxylic acids, and their derivatives (esters, amides, acid chlorides). Key reactions include nucleophilic addition, Aldol condensation, Cannizzaro, and Claisen. Very heavily tested in JEE and NEET.

Read the full Aldehydes, Ketones and Carboxylic Acids notes →