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🧪 Chemistry  ·  Aldehydes, Ketones and Carboxylic Acids  ·  NEET & JEE

What is the product of the reaction of formaldehyde with excess Grignard reagent (RMgX)?

Answer: Primary alcohol.

  • A Primary alcohol
  • B Secondary alcohol
  • C Tertiary alcohol
  • D Ester

Correct answer: A. Primary alcohol

Explanation: Formaldehyde has only one carbon; addition of RMgX followed by hydrolysis gives a primary alcohol RCH<sub>2</sub>OH.

Nucleophilic Addition to C=ONu:-CORR'CO-RR'Nu

Curved arrows show the nucleophile attacking the carbonyl carbon while the C=O pi electrons move onto oxygen, giving a tetrahedral alkoxide intermediate.

Concept context

Aldehydes, ketones, carboxylic acids, and their derivatives (esters, amides, acid chlorides). Key reactions include nucleophilic addition, Aldol condensation, Cannizzaro, and Claisen. Very heavily tested in JEE and NEET.

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