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🧪 Chemistry  ·  Aldehydes, Ketones and Carboxylic Acids  ·  NEET & JEE

Grignard reagent reacts with formaldehyde to give (after hydrolysis):

Answer: Primary alcohol.

  • A Primary alcohol
  • B Secondary alcohol
  • C Tertiary alcohol
  • D Carboxylic acid

Correct answer: A. Primary alcohol

Explanation: Formaldehyde has only one carbon; the Grignard product after hydrolysis is a primary alcohol.

Nucleophilic Addition to C=ONu:-CORR'CO-RR'Nu

Curved arrows show the nucleophile attacking the carbonyl carbon while the C=O pi electrons move onto oxygen, giving a tetrahedral alkoxide intermediate.

Concept context

Aldehydes, ketones, carboxylic acids, and their derivatives (esters, amides, acid chlorides). Key reactions include nucleophilic addition, Aldol condensation, Cannizzaro, and Claisen. Very heavily tested in JEE and NEET.

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