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🧪 Chemistry  ·  Aldehydes, Ketones and Carboxylic Acids  ·  NEET & JEE

Grignard reagent reacts with a ketone to give (after hydrolysis):

Answer: Tertiary alcohol.

  • A Primary alcohol
  • B Secondary alcohol
  • C Tertiary alcohol
  • D Ester

Correct answer: C. Tertiary alcohol

Explanation: Ketones give tertiary alcohols with Grignard reagents.

Nucleophilic Addition to C=ONu:-CORR'CO-RR'Nu

Curved arrows show the nucleophile attacking the carbonyl carbon while the C=O pi electrons move onto oxygen, giving a tetrahedral alkoxide intermediate.

Concept context

Aldehydes, ketones, carboxylic acids, and their derivatives (esters, amides, acid chlorides). Key reactions include nucleophilic addition, Aldol condensation, Cannizzaro, and Claisen. Very heavily tested in JEE and NEET.

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