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🧪 Chemistry  ·  Aldehydes, Ketones and Carboxylic Acids  ·  NEET & JEE

Fehling's solution gives a brick-red precipitate with:

Answer: Aliphatic aldehydes.

  • A Ketones
  • B Aliphatic aldehydes
  • C Aromatic aldehydes
  • D Ethers

Correct answer: B. Aliphatic aldehydes

Explanation: Aliphatic aldehydes reduce Fehling's solution to give Cu<sub>2</sub>O (brick-red precipitate).

Nucleophilic Addition to C=ONu:-CORR'CO-RR'Nu

Curved arrows show the nucleophile attacking the carbonyl carbon while the C=O pi electrons move onto oxygen, giving a tetrahedral alkoxide intermediate.

Concept context

Aldehydes, ketones, carboxylic acids, and their derivatives (esters, amides, acid chlorides). Key reactions include nucleophilic addition, Aldol condensation, Cannizzaro, and Claisen. Very heavily tested in JEE and NEET.

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