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🧪 Chemistry  ·  Alcohols, Phenols & Ethers  ·  NEET & JEE

Which product is formed in Kolbe reaction of sodium phenoxide with CO<sub>2</sub>?

Answer: Salicylic acid.

  • A Salicylic acid
  • B Benzoic acid
  • C Phenol
  • D Benzaldehyde

Correct answer: A. Salicylic acid

Explanation: Kolbe reaction introduces a carboxyl group ortho to the OH group forming salicylic acid.

Why Phenol Is More Acidic Than an AlcoholO⁻phenoxide ioncharge delocalised into ring (resonance)stabilisedCO⁻alkoxide ion (ethanol)charge stuck on one O, NOT stabilised

The phenoxide ion's negative charge spreads into the aromatic ring through resonance, lowering its energy and making phenol give up its proton more easily; an alkoxide ion (from a plain alcohol) has nowhere to delocalise the charge, making alcohols far less acidic.

Concept context

Oxygen-containing organic compounds. Understand the acidic nature of phenols, reactions of alcohols (dehydration, oxidation, esterification), and properties of ethers. Includes industrial applications and named reactions.

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